Fine-tuning of a ferrocene[porphyrin]ITO redox cascade for efficient sequential electron transfer commenced by an S2 photoexcited special-pair mimic.
نویسندگان
چکیده
A systematic series of ferrocene/porphyrin redox cascade architectures was assembled through a slipped-cofacial porphyrin dimer on ITO electrode in optimizing the anodic photocurrent generation to perform the highest quantum yield compared to reported values on ITO electrodes.
منابع مشابه
Photoinduced Electron Transfer Reactions in a Porphyrin-Viologen Complex: Observation of S2 to S1 Relaxation and Electron Transfer from the S2 State
Andersson, M. 2000. Tuning Electron Transfer Reactions by Selective Excitation in Porphyrin Acceptor Assemblies. Acta Universitatis Upsaliensis. Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology 578. 58 pp. Uppsala. ISBN 91-554-48437. This thesis concerns electron transfer reactions from different excited states in porphyrins, and the effect of changing...
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عنوان ژورنال:
- Chemical communications
دوره 23 شماره
صفحات -
تاریخ انتشار 2007